Tripalladium(0) sandwich complexes with nitrogen based ligands

John C. Charbonneau; Cory B. Cluff; Hannah R. Babbini; Dominic C. Babbini; Gary S. Nichol; Stephanie K. Hurst

doi:10.1016/j.poly.2016.03.027

Tripalladium(0) sandwich complexes with nitrogen based ligands

John C. Charbonneau, Cory B. Cluff, Hannah R. Babbini, Dominic C. Babbini, Gary S. Nichol, Stephanie K. Hurst

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd₃Tr₂]²⁺ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.

Original language	English (US)
Pages (from-to)	443-450
Number of pages	8
Journal	Polyhedron
Volume	114
DOIs	https://doi.org/10.1016/j.poly.2016.03.027
State	Published - Aug 16 2016

Keywords

Nitrile
Pyridine
Sandwich
Tripalladium
Tropylium

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.poly.2016.03.027

Cite this

@article{1a4f3fd5a4be45aca11506c7d10d9b2c,

title = "Tripalladium(0) sandwich complexes with nitrogen based ligands",

abstract = "The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.",

keywords = "Nitrile, Pyridine, Sandwich, Tripalladium, Tropylium",

author = "Charbonneau, {John C.} and Cluff, {Cory B.} and Babbini, {Hannah R.} and Babbini, {Dominic C.} and Nichol, {Gary S.} and Hurst, {Stephanie K.}",

year = "2016",

month = aug,

day = "16",

doi = "10.1016/j.poly.2016.03.027",

language = "English (US)",

volume = "114",

pages = "443--450",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Tripalladium(0) sandwich complexes with nitrogen based ligands

AU - Charbonneau, John C.

AU - Cluff, Cory B.

AU - Babbini, Hannah R.

AU - Babbini, Dominic C.

AU - Nichol, Gary S.

AU - Hurst, Stephanie K.

PY - 2016/8/16

Y1 - 2016/8/16

N2 - The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.

AB - The synthesis and characterization of a series of complexes based upon a central tripalladium ditropylium (Tr) unit [Pd3Tr2]2+ containing different nitrogen-based ligands is reported. The complexes were synthesized in good yield and characterized by multi-nuclei NMR spectroscopy, elemental microanalysis and single-crystal X-ray crystallography. Variation in the equatorial ligand strongly influences Pd-N bond distances, but has only a minor effect on Pd-Pd distances. These complexes provide insight into the synthesis of materials of higher dimensionality.

KW - Nitrile

KW - Pyridine

KW - Sandwich

KW - Tripalladium

KW - Tropylium

UR - http://www.scopus.com/inward/record.url?scp=84974698226&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84974698226&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2016.03.027

DO - 10.1016/j.poly.2016.03.027

M3 - Article

AN - SCOPUS:84974698226

SN - 0277-5387

VL - 114

SP - 443

EP - 450

JO - Polyhedron

JF - Polyhedron

ER -

Tripalladium(0) sandwich complexes with nitrogen based ligands

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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CCDC 1428954: Experimental Crystal Structure Determination

CCDC 1429150: Experimental Crystal Structure Determination

CCDC 1428956: Experimental Crystal Structure Determination

Cite this

Tripalladium(0) sandwich complexes with nitrogen based ligands

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1428954: Experimental Crystal Structure Determination

CCDC 1429150: Experimental Crystal Structure Determination

CCDC 1428956: Experimental Crystal Structure Determination

Cite this