Tetraalkylphosphonium-based ionic liquids for a single-step dye extraction/MALDI MS analysis platform

Katherine S. Lovejoy; Geraldine M. Purdy; Srinivas Iyer; Timothy C. Sanchez; Al Robertson; Andrew T. Koppisch; Rico E. Del Sesto

doi:10.1021/ac102944w

Tetraalkylphosphonium-based ionic liquids for a single-step dye extraction/MALDI MS analysis platform

Katherine S. Lovejoy, Geraldine M. Purdy, Srinivas Iyer, Timothy C. Sanchez, Al Robertson, Andrew T. Koppisch, Rico E. Del Sesto

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Room temperature ionic liquids, or RTILs, based on tetraalkylphosphonium (PR₄⁺) cations were used as the basis of a platform that enables separation of dyes from textiles, extraction of dyes from aqueous solution, and identification of the dyes by MALDI-MS in a single experimental step for forensic purposes. Ionic liquids were formed with PR₄ ⁺ cations and ferulate (FA), α-cyano-4-hydroxycinnamate (CHCA), and 2,5-dihydroxybenzoate (DHB) anions. The use of tetraalkylphosphonium-based ionic liquids in MALDI-MS allowed detection of small molecule dyes without addition of a traditional solid MALDI matrix.

Original language	English (US)
Pages (from-to)	2921-2930
Number of pages	10
Journal	Analytical Chemistry
Volume	83
Issue number	8
DOIs	https://doi.org/10.1021/ac102944w
State	Published - Apr 15 2011

ASJC Scopus subject areas

Analytical Chemistry

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10.1021/ac102944w

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title = "Tetraalkylphosphonium-based ionic liquids for a single-step dye extraction/MALDI MS analysis platform",

abstract = "Room temperature ionic liquids, or RTILs, based on tetraalkylphosphonium (PR4+) cations were used as the basis of a platform that enables separation of dyes from textiles, extraction of dyes from aqueous solution, and identification of the dyes by MALDI-MS in a single experimental step for forensic purposes. Ionic liquids were formed with PR4 + cations and ferulate (FA), α-cyano-4-hydroxycinnamate (CHCA), and 2,5-dihydroxybenzoate (DHB) anions. The use of tetraalkylphosphonium-based ionic liquids in MALDI-MS allowed detection of small molecule dyes without addition of a traditional solid MALDI matrix.",

author = "Lovejoy, {Katherine S.} and Purdy, {Geraldine M.} and Srinivas Iyer and Sanchez, {Timothy C.} and Al Robertson and Koppisch, {Andrew T.} and {Del Sesto}, {Rico E.}",

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T1 - Tetraalkylphosphonium-based ionic liquids for a single-step dye extraction/MALDI MS analysis platform

AU - Lovejoy, Katherine S.

AU - Purdy, Geraldine M.

AU - Iyer, Srinivas

AU - Sanchez, Timothy C.

AU - Robertson, Al

AU - Koppisch, Andrew T.

AU - Del Sesto, Rico E.

PY - 2011/4/15

Y1 - 2011/4/15

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AB - Room temperature ionic liquids, or RTILs, based on tetraalkylphosphonium (PR4+) cations were used as the basis of a platform that enables separation of dyes from textiles, extraction of dyes from aqueous solution, and identification of the dyes by MALDI-MS in a single experimental step for forensic purposes. Ionic liquids were formed with PR4 + cations and ferulate (FA), α-cyano-4-hydroxycinnamate (CHCA), and 2,5-dihydroxybenzoate (DHB) anions. The use of tetraalkylphosphonium-based ionic liquids in MALDI-MS allowed detection of small molecule dyes without addition of a traditional solid MALDI matrix.

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Tetraalkylphosphonium-based ionic liquids for a single-step dye extraction/MALDI MS analysis platform

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