Spectroscopic manifestations of structural shell filling in (benzene)n clusters, N = 1-20

David C. Easter, M. S. El-Shall, M. Y. Hahn, R. L. Whetten

Research output: Contribution to journalArticlepeer-review

35 Scopus citations

Abstract

Well resolved ultraviolet spectra of the smaller benzene clusters (BN, N≤20) have been obtained by resonant two-photon ionization spectroscopy of a cluster beam. Under the coldest conditions, optical lineshapes show a remarkable narrowing at N = 13, and probable secondary linewidth minima at N = 7 and 19. This pattern is interpreted according to the principles of shell filling in clusters of nonpolar molecules.

Original languageEnglish (US)
Pages (from-to)277-282
Number of pages6
JournalChemical Physics Letters
Volume157
Issue number4
DOIs
StatePublished - May 12 1989
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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