Semiclassical eigenvalues for a non-adiabatic system

J. W. Zwanziger, R. L. Whetten, G. S. Ezra, E. R. Grant

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

We have performed a semiclassical quantization of the Meyer-Miller classical analog Hamiltonian for the Jahn-Teller E × e system, in the regime of small linear coupling. The primitive semiclassical energies are in good qualitative and reasonable quantitative agreement with the exact quantum-mechanical solution to this problem. These results demonstrate that such a classical model is able to accurately describe the behavior of non-adiabatic bound state systems, but that uniformization will be necessary to obtain more precise agreement with quantum mechanics.

Original languageEnglish (US)
Pages (from-to)106-112
Number of pages7
JournalChemical Physics Letters
Volume120
Issue number1
DOIs
StatePublished - Sep 27 1985
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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