Organometallic complexes for nonlinear optics. 28. Dimensional evolution of quadratic and cubic optical nonlinearities in stilbenylethynylruthenium complexes

Stephanie K. Hurst; Mark G. Humphrey; Takashi Isoshima; Kurt Wostyn; Inge Asselberghs; Koen Clays; André Persoons; Marek Samoc; Barry Luther-Davies

doi:10.1021/om020008c

Organometallic complexes for nonlinear optics. 28. Dimensional evolution of quadratic and cubic optical nonlinearities in stilbenylethynylruthenium complexes

Stephanie K. Hurst, Mark G. Humphrey, Takashi Isoshima, Kurt Wostyn, Inge Asselberghs, Koen Clays, André Persoons, Marek Samoc, Barry Luther-Davies

Chemistry and Biochemistry

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72 Scopus citations

Abstract

The use of organometallic complexes for nonlinear optics was discussed. Cubic nonlinearities \γ\₈₀₀ and two-photon absorption cross-sections σ₂ increase on 'dimensional evolution' from linear analogues to octopolar complexes. Molecular third-order nonlinear susceptibilities χ⁽³⁾ were also found to be large and scaling with the number of metal atoms.

Original language	English (US)
Pages (from-to)	2024-2026
Number of pages	3
Journal	Organometallics
Volume	21
Issue number	10
DOIs	https://doi.org/10.1021/om020008c
State	Published - May 13 2002

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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AU - Hurst, Stephanie K.

AU - Humphrey, Mark G.

AU - Isoshima, Takashi

AU - Wostyn, Kurt

AU - Asselberghs, Inge

AU - Clays, Koen

AU - Persoons, André

AU - Samoc, Marek

AU - Luther-Davies, Barry

PY - 2002/5/13

Y1 - 2002/5/13

N2 - The use of organometallic complexes for nonlinear optics was discussed. Cubic nonlinearities \γ\800 and two-photon absorption cross-sections σ2 increase on 'dimensional evolution' from linear analogues to octopolar complexes. Molecular third-order nonlinear susceptibilities χ(3) were also found to be large and scaling with the number of metal atoms.

AB - The use of organometallic complexes for nonlinear optics was discussed. Cubic nonlinearities \γ\800 and two-photon absorption cross-sections σ2 increase on 'dimensional evolution' from linear analogues to octopolar complexes. Molecular third-order nonlinear susceptibilities χ(3) were also found to be large and scaling with the number of metal atoms.

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Organometallic complexes for nonlinear optics. 28. Dimensional evolution of quadratic and cubic optical nonlinearities in stilbenylethynylruthenium complexes

Abstract

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