Organometallic complexes for nonlinear optics. 28. Dimensional evolution of quadratic and cubic optical nonlinearities in stilbenylethynylruthenium complexes

Stephanie K. Hurst; Mark G. Humphrey; Takashi Isoshima; Kurt Wostyn; Inge Asselberghs; Koen Clays; André Persoons; Marek Samoc; Barry Luther-Davies

doi:10.1021/om020008c

Organometallic complexes for nonlinear optics. 28. Dimensional evolution of quadratic and cubic optical nonlinearities in stilbenylethynylruthenium complexes

Stephanie K. Hurst
, Mark G. Humphrey
, Takashi Isoshima
, Kurt Wostyn
, Inge Asselberghs
, Koen Clays
, André Persoons
, Marek Samoc
, Barry Luther-Davies

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

The use of organometallic complexes for nonlinear optics was discussed. Cubic nonlinearities \γ\₈₀₀ and two-photon absorption cross-sections σ₂ increase on 'dimensional evolution' from linear analogues to octopolar complexes. Molecular third-order nonlinear susceptibilities χ⁽³⁾ were also found to be large and scaling with the number of metal atoms.

Original language	English (US)
Pages (from-to)	2024-2026
Number of pages	3
Journal	Organometallics
Volume	21
Issue number	10
DOIs	https://doi.org/10.1021/om020008c
State	Published - May 13 2002

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om020008c

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abstract = "The use of organometallic complexes for nonlinear optics was discussed. Cubic nonlinearities \textbackslash{}γ\textbackslash{}800 and two-photon absorption cross-sections σ2 increase on 'dimensional evolution' from linear analogues to octopolar complexes. Molecular third-order nonlinear susceptibilities χ(3) were also found to be large and scaling with the number of metal atoms.",

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AU - Hurst, Stephanie K.

AU - Humphrey, Mark G.

AU - Isoshima, Takashi

AU - Wostyn, Kurt

AU - Asselberghs, Inge

AU - Clays, Koen

AU - Persoons, André

AU - Samoc, Marek

AU - Luther-Davies, Barry

PY - 2002/5/13

Y1 - 2002/5/13

N2 - The use of organometallic complexes for nonlinear optics was discussed. Cubic nonlinearities \γ\800 and two-photon absorption cross-sections σ2 increase on 'dimensional evolution' from linear analogues to octopolar complexes. Molecular third-order nonlinear susceptibilities χ(3) were also found to be large and scaling with the number of metal atoms.

AB - The use of organometallic complexes for nonlinear optics was discussed. Cubic nonlinearities \γ\800 and two-photon absorption cross-sections σ2 increase on 'dimensional evolution' from linear analogues to octopolar complexes. Molecular third-order nonlinear susceptibilities χ(3) were also found to be large and scaling with the number of metal atoms.

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Organometallic complexes for nonlinear optics. 28. Dimensional evolution of quadratic and cubic optical nonlinearities in stilbenylethynylruthenium complexes

Abstract

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