New trimetallic sandwich complexes of platinum(0) and palladium(0)

Dominic C. Babbini; Kyle J. Cluff; Nathan B. Fisher; John C. Charbonneau; Gary S. Nichol; Stephanie K. Hurst

doi:10.1016/j.jorganchem.2012.03.033

New trimetallic sandwich complexes of platinum(0) and palladium(0)

Dominic C. Babbini, Kyle J. Cluff, Nathan B. Fisher, John C. Charbonneau, Gary S. Nichol, Stephanie K. Hurst

Chemistry and Biochemistry

Research output: Contribution to journal › Short survey › peer-review

14 Scopus citations

Abstract

The synthesis and characterization of a series of complexes based upon a central triplatinum ditropylium (Tr) unit [Pt₃Tr₂] ²⁺ containing different halide ligands is reported. The complexes were synthesized in moderate yield and characterized by multi-nuclei NMR spectroscopy, mass spectrometry, microanalysis and X-ray crystallography. In addition it was demonstrated that mixed-metal, palladium-platinum sandwich complexes could also be formed [Pd_nPt_3-nTr ₂X₃][Y] (X = Cl, Br and I, Y = NBu₄ ⁺ or PBu₄ ⁺).

Original language	English (US)
Pages (from-to)	217-221
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	713
DOIs	https://doi.org/10.1016/j.jorganchem.2012.03.033
State	Published - Aug 15 2012

Keywords

Organometallic
Palladium
Platinum
Tropylium

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2012.03.033

Cite this

@article{f170128ccd114e6b8ba61a63bf96b910,

title = "New trimetallic sandwich complexes of platinum(0) and palladium(0)",

abstract = "The synthesis and characterization of a series of complexes based upon a central triplatinum ditropylium (Tr) unit [Pt3Tr2] 2+ containing different halide ligands is reported. The complexes were synthesized in moderate yield and characterized by multi-nuclei NMR spectroscopy, mass spectrometry, microanalysis and X-ray crystallography. In addition it was demonstrated that mixed-metal, palladium-platinum sandwich complexes could also be formed [PdnPt3-nTr 2X3][Y] (X = Cl, Br and I, Y = NBu4 + or PBu4 +).",

keywords = "Organometallic, Palladium, Platinum, Tropylium",

author = "Babbini, {Dominic C.} and Cluff, {Kyle J.} and Fisher, {Nathan B.} and Charbonneau, {John C.} and Nichol, {Gary S.} and Hurst, {Stephanie K.}",

note = "Funding Information: We thank Northern Arizona University and the College of Engineering, Forestry and Natural Sciences for start up funding. The X-ray diffractometer for 1 was purchased with funds from NSF grant CHE-9610374 . Crystallographic data for 2 was collected at Beamline 11.3.1 at the Advanced Light Source (ALS), Lawrence Berkeley National Laboratory. The ALS is supported by the U.S. Department of Energy, Office of Energy Sciences , under Contract DE-AC02-05CH11231 . We thank the Research Corporation for Science Advancement for their support though the Cottrell College Science Award ( ID 10600 ). We also thank Dr. Brian Cherry of the Magnetic Resonance Center Research at Arizona State University for collection of 195 Pt NMR spectra. We also wish to thank the American Chemical Society Petroleum Research Fund (ACS-PRF) for funding. ",

year = "2012",

month = aug,

day = "15",

doi = "10.1016/j.jorganchem.2012.03.033",

language = "English (US)",

volume = "713",

pages = "217--221",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - New trimetallic sandwich complexes of platinum(0) and palladium(0)

AU - Babbini, Dominic C.

AU - Cluff, Kyle J.

AU - Fisher, Nathan B.

AU - Charbonneau, John C.

AU - Nichol, Gary S.

AU - Hurst, Stephanie K.

N1 - Funding Information: We thank Northern Arizona University and the College of Engineering, Forestry and Natural Sciences for start up funding. The X-ray diffractometer for 1 was purchased with funds from NSF grant CHE-9610374 . Crystallographic data for 2 was collected at Beamline 11.3.1 at the Advanced Light Source (ALS), Lawrence Berkeley National Laboratory. The ALS is supported by the U.S. Department of Energy, Office of Energy Sciences , under Contract DE-AC02-05CH11231 . We thank the Research Corporation for Science Advancement for their support though the Cottrell College Science Award ( ID 10600 ). We also thank Dr. Brian Cherry of the Magnetic Resonance Center Research at Arizona State University for collection of 195 Pt NMR spectra. We also wish to thank the American Chemical Society Petroleum Research Fund (ACS-PRF) for funding.

PY - 2012/8/15

Y1 - 2012/8/15

N2 - The synthesis and characterization of a series of complexes based upon a central triplatinum ditropylium (Tr) unit [Pt3Tr2] 2+ containing different halide ligands is reported. The complexes were synthesized in moderate yield and characterized by multi-nuclei NMR spectroscopy, mass spectrometry, microanalysis and X-ray crystallography. In addition it was demonstrated that mixed-metal, palladium-platinum sandwich complexes could also be formed [PdnPt3-nTr 2X3][Y] (X = Cl, Br and I, Y = NBu4 + or PBu4 +).

AB - The synthesis and characterization of a series of complexes based upon a central triplatinum ditropylium (Tr) unit [Pt3Tr2] 2+ containing different halide ligands is reported. The complexes were synthesized in moderate yield and characterized by multi-nuclei NMR spectroscopy, mass spectrometry, microanalysis and X-ray crystallography. In addition it was demonstrated that mixed-metal, palladium-platinum sandwich complexes could also be formed [PdnPt3-nTr 2X3][Y] (X = Cl, Br and I, Y = NBu4 + or PBu4 +).

KW - Organometallic

KW - Palladium

KW - Platinum

KW - Tropylium

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U2 - 10.1016/j.jorganchem.2012.03.033

DO - 10.1016/j.jorganchem.2012.03.033

M3 - Short survey

AN - SCOPUS:84862630775

SN - 0022-328X

VL - 713

SP - 217

EP - 221

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

New trimetallic sandwich complexes of platinum(0) and palladium(0)

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 795493: Experimental Crystal Structure Determination

CCDC 796540: Experimental Crystal Structure Determination

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New trimetallic sandwich complexes of platinum(0) and palladium(0)

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 795493: Experimental Crystal Structure Determination

CCDC 796540: Experimental Crystal Structure Determination

Cite this