Nanoparticle filled rubbery polymer membranes for CO2 sequestration

Scott T. Matteucci; Haiqing Lin; Benny Freeman; Victor Kusuma; Miquel Jose-Yacaman; Sumod Kalakkunnath; Douglass S. Kalika

Nanoparticle filled rubbery polymer membranes for CO₂ sequestration

Scott T. Matteucci, Haiqing Lin, Benny Freeman, Victor Kusuma, Miquel Jose-Yacaman, Sumod Kalakkunnath, Douglass S. Kalika

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

Nonporous metal oxide nanoparticles (primary particle diameter as low as 2.5 nm) have been dispersed in rubbery polymer to make membranes that have over an order of magnitude higher light gas (i.e., CO₂, N₂, O₂, H₂) permeability with little or no change in selectivity relative to the neat polymer, which runs counter to traditional filled rubbery polymers. For example, the CO₂ permeability was 1100 barrers in filled 1,2-butadiene as compared to 52 barrers for the unfilled polymer. For both materials, the CO₂/N₂ selectivity was 14, at 35°C and 3.4 atm. Nanoparticle filled poly(ethylene oxide) membranes reached permeabilities as high as 1700 barrer while maintaining a CO₂/N₂ selectivity of 25, at 35°C and 3.4 atm. The degree of permeability enhancement is particle loading dependent, with maximum particle loading over 50 wt % for some materials. This is an abstract of a paper presented at the AIChE Annual Meeting and Fall Showcase (Cincinnati, OH 10/30/2005-11/4/2005).

Original language	English (US)
Title of host publication	05AIChE
Subtitle of host publication	2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings
Publisher	American Institute of Chemical Engineers
ISBN (Print)	0816909962, 9780816909964
State	Published - 2005
Externally published	Yes
Event	05AIChE: 2005 AIChE Annual Meeting and Fall Showcase - Cincinnati, OH, United States Duration: Oct 30 2005 → Nov 4 2005

Publication series

Name	AIChE Annual Meeting Conference Proceedings
Volume	2005

Conference

Conference	05AIChE: 2005 AIChE Annual Meeting and Fall Showcase
Country/Territory	United States
City	Cincinnati, OH
Period	10/30/05 → 11/4/05

ASJC Scopus subject areas

General Energy

Cite this

Nanoparticle filled rubbery polymer membranes for CO₂ sequestration. / Matteucci, Scott T.; Lin, Haiqing; Freeman, Benny et al.
05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings. American Institute of Chemical Engineers, 2005. (AIChE Annual Meeting Conference Proceedings; Vol. 2005).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Matteucci, ST, Lin, H, Freeman, B, Kusuma, V, Jose-Yacaman, M, Kalakkunnath, S & Kalika, DS 2005, Nanoparticle filled rubbery polymer membranes for CO₂ sequestration. in 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings. AIChE Annual Meeting Conference Proceedings, vol. 2005, American Institute of Chemical Engineers, 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Cincinnati, OH, United States, 10/30/05.

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abstract = "Nonporous metal oxide nanoparticles (primary particle diameter as low as 2.5 nm) have been dispersed in rubbery polymer to make membranes that have over an order of magnitude higher light gas (i.e., CO2, N2, O2, H2) permeability with little or no change in selectivity relative to the neat polymer, which runs counter to traditional filled rubbery polymers. For example, the CO2 permeability was 1100 barrers in filled 1,2-butadiene as compared to 52 barrers for the unfilled polymer. For both materials, the CO2/N2 selectivity was 14, at 35°C and 3.4 atm. Nanoparticle filled poly(ethylene oxide) membranes reached permeabilities as high as 1700 barrer while maintaining a CO2/N2 selectivity of 25, at 35°C and 3.4 atm. The degree of permeability enhancement is particle loading dependent, with maximum particle loading over 50 wt % for some materials. This is an abstract of a paper presented at the AIChE Annual Meeting and Fall Showcase (Cincinnati, OH 10/30/2005-11/4/2005).",

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AU - Kalakkunnath, Sumod

AU - Kalika, Douglass S.

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N2 - Nonporous metal oxide nanoparticles (primary particle diameter as low as 2.5 nm) have been dispersed in rubbery polymer to make membranes that have over an order of magnitude higher light gas (i.e., CO2, N2, O2, H2) permeability with little or no change in selectivity relative to the neat polymer, which runs counter to traditional filled rubbery polymers. For example, the CO2 permeability was 1100 barrers in filled 1,2-butadiene as compared to 52 barrers for the unfilled polymer. For both materials, the CO2/N2 selectivity was 14, at 35°C and 3.4 atm. Nanoparticle filled poly(ethylene oxide) membranes reached permeabilities as high as 1700 barrer while maintaining a CO2/N2 selectivity of 25, at 35°C and 3.4 atm. The degree of permeability enhancement is particle loading dependent, with maximum particle loading over 50 wt % for some materials. This is an abstract of a paper presented at the AIChE Annual Meeting and Fall Showcase (Cincinnati, OH 10/30/2005-11/4/2005).

AB - Nonporous metal oxide nanoparticles (primary particle diameter as low as 2.5 nm) have been dispersed in rubbery polymer to make membranes that have over an order of magnitude higher light gas (i.e., CO2, N2, O2, H2) permeability with little or no change in selectivity relative to the neat polymer, which runs counter to traditional filled rubbery polymers. For example, the CO2 permeability was 1100 barrers in filled 1,2-butadiene as compared to 52 barrers for the unfilled polymer. For both materials, the CO2/N2 selectivity was 14, at 35°C and 3.4 atm. Nanoparticle filled poly(ethylene oxide) membranes reached permeabilities as high as 1700 barrer while maintaining a CO2/N2 selectivity of 25, at 35°C and 3.4 atm. The degree of permeability enhancement is particle loading dependent, with maximum particle loading over 50 wt % for some materials. This is an abstract of a paper presented at the AIChE Annual Meeting and Fall Showcase (Cincinnati, OH 10/30/2005-11/4/2005).

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