Nanocrystallization behavior and magnetic properties of amorphous Fe78Si9B13 ribbons

Xiangcheng Sun; A. Cabral-Prieto; M. Jose Yacaman; J. Reyes-Gasga; R. Hernandez-Reyes; A. Morales; Wensheng Sun

doi:10.1016/S0921-4526(99)01241-7

Nanocrystallization behavior and magnetic properties of amorphous Fe₇₈Si₉B₁₃ ribbons

Xiangcheng Sun
, A. Cabral-Prieto
, M. Jose Yacaman
, J. Reyes-Gasga
, R. Hernandez-Reyes
, A. Morales
, Wensheng Sun

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The amorphous state of ferromagnetic Fe₇₈Si₉B₁₃ ribbons and its nanocrystallization were investigated by in situ transmission electron microscope (TEM), X-ray diffraction (XRD), Mossbauer spectroscopy (MS), differential scanning calorimeters (DSC) and magnetic moment measurements. The Mossbauer spectrum exhibited an essentially symmetric hyperfine field pattern of 259 kOe in as-quenched amorphous state at room temperature. The Curie and crystallization temperature were determined to be T_c = 708 K and T_x = 803 K, respectively. The T_x value was in good agreement with DSC measurement results. The occupied fraction of the nanocrystalline phases of α-Fe(Si) and Fe₂B at in situ optimum annealing temperature was about 57% and 43%, respectively. It is notable that the magnetization of the amorphous phase decreases more rapidly with increasing temperature than those of nanocrystalline ferromagnetism, suggesting the presence of the distribution of exchange interaction in the amorphous phase or high metalloid contents.

Original language	English (US)
Pages (from-to)	173-179
Number of pages	7
Journal	Physica B: Condensed Matter
Volume	291
Issue number	1-2
DOIs	https://doi.org/10.1016/S0921-4526(99)01241-7
State	Published - Aug 2000
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering

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10.1016/S0921-4526(99)01241-7

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@article{c6e28d22a0244354ae49a73610690324,

title = "Nanocrystallization behavior and magnetic properties of amorphous Fe78Si9B13 ribbons",

abstract = "The amorphous state of ferromagnetic Fe78Si9B13 ribbons and its nanocrystallization were investigated by in situ transmission electron microscope (TEM), X-ray diffraction (XRD), Mossbauer spectroscopy (MS), differential scanning calorimeters (DSC) and magnetic moment measurements. The Mossbauer spectrum exhibited an essentially symmetric hyperfine field pattern of 259 kOe in as-quenched amorphous state at room temperature. The Curie and crystallization temperature were determined to be Tc = 708 K and Tx = 803 K, respectively. The Tx value was in good agreement with DSC measurement results. The occupied fraction of the nanocrystalline phases of α-Fe(Si) and Fe2B at in situ optimum annealing temperature was about 57\% and 43\%, respectively. It is notable that the magnetization of the amorphous phase decreases more rapidly with increasing temperature than those of nanocrystalline ferromagnetism, suggesting the presence of the distribution of exchange interaction in the amorphous phase or high metalloid contents.",

author = "Xiangcheng Sun and A. Cabral-Prieto and \{Jose Yacaman\}, M. and J. Reyes-Gasga and R. Hernandez-Reyes and A. Morales and Wensheng Sun",

note = "Funding Information: The present work is financially supported by CONACyT projects through “Quantum Colliods” in Mexico. The authors are grateful to Mr. C. Rodriguez for DSC measurements and Ms. Thelma at XRD analysis.",

year = "2000",

month = aug,

doi = "10.1016/S0921-4526(99)01241-7",

language = "English (US)",

volume = "291",

pages = "173--179",

journal = "Physica B: Condensed Matter",

issn = "0921-4526",

publisher = "Elsevier B.V.",

number = "1-2",

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TY - JOUR

T1 - Nanocrystallization behavior and magnetic properties of amorphous Fe78Si9B13 ribbons

AU - Sun, Xiangcheng

AU - Cabral-Prieto, A.

AU - Jose Yacaman, M.

AU - Reyes-Gasga, J.

AU - Hernandez-Reyes, R.

AU - Morales, A.

AU - Sun, Wensheng

N1 - Funding Information: The present work is financially supported by CONACyT projects through “Quantum Colliods” in Mexico. The authors are grateful to Mr. C. Rodriguez for DSC measurements and Ms. Thelma at XRD analysis.

PY - 2000/8

Y1 - 2000/8

N2 - The amorphous state of ferromagnetic Fe78Si9B13 ribbons and its nanocrystallization were investigated by in situ transmission electron microscope (TEM), X-ray diffraction (XRD), Mossbauer spectroscopy (MS), differential scanning calorimeters (DSC) and magnetic moment measurements. The Mossbauer spectrum exhibited an essentially symmetric hyperfine field pattern of 259 kOe in as-quenched amorphous state at room temperature. The Curie and crystallization temperature were determined to be Tc = 708 K and Tx = 803 K, respectively. The Tx value was in good agreement with DSC measurement results. The occupied fraction of the nanocrystalline phases of α-Fe(Si) and Fe2B at in situ optimum annealing temperature was about 57% and 43%, respectively. It is notable that the magnetization of the amorphous phase decreases more rapidly with increasing temperature than those of nanocrystalline ferromagnetism, suggesting the presence of the distribution of exchange interaction in the amorphous phase or high metalloid contents.

AB - The amorphous state of ferromagnetic Fe78Si9B13 ribbons and its nanocrystallization were investigated by in situ transmission electron microscope (TEM), X-ray diffraction (XRD), Mossbauer spectroscopy (MS), differential scanning calorimeters (DSC) and magnetic moment measurements. The Mossbauer spectrum exhibited an essentially symmetric hyperfine field pattern of 259 kOe in as-quenched amorphous state at room temperature. The Curie and crystallization temperature were determined to be Tc = 708 K and Tx = 803 K, respectively. The Tx value was in good agreement with DSC measurement results. The occupied fraction of the nanocrystalline phases of α-Fe(Si) and Fe2B at in situ optimum annealing temperature was about 57% and 43%, respectively. It is notable that the magnetization of the amorphous phase decreases more rapidly with increasing temperature than those of nanocrystalline ferromagnetism, suggesting the presence of the distribution of exchange interaction in the amorphous phase or high metalloid contents.

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U2 - 10.1016/S0921-4526(99)01241-7

DO - 10.1016/S0921-4526(99)01241-7

M3 - Article

AN - SCOPUS:0034250867

SN - 0921-4526

VL - 291

SP - 173

EP - 179

JO - Physica B: Condensed Matter

JF - Physica B: Condensed Matter

IS - 1-2

ER -

Nanocrystallization behavior and magnetic properties of amorphous Fe₇₈Si₉B₁₃ ribbons

Abstract

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