Monomers and polymers of tripalladium(0) ditropylium halides

Frank L. Mulligan; Dominic C. Babbini; Isaac R. Davis; Stephanie K. Hurst; Gary S. Nichol

doi:10.1021/ic8014578

Monomers and polymers of tripalladium(0) ditropylium halides

Frank L. Mulligan
, Dominic C. Babbini
, Isaac R. Davis
, Stephanie K. Hurst
, Gary S. Nichol

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The synthesis and characterization of a series of polymeric complexes based upon a central tripalladium ditropylium (Tr) unit [Pd ₃Tr ₂] and containing different halide ligands are reported. The complexes were synthesized in good yield and characterized by multinuclei NMR spectroscopy, mass spectrometry, microanalysis, and X-ray crystallography. An unexpected product was an inorganic polymer consisting of linked individual tripalladium ditropylium units [Pd ₃Tr ₂X ₂] _∞ (X = Cl, Br, and I); this is the first reported, crystallographically characterized example of polymeric tripalladium complexes with halide ligands.

Original language	English (US)
Pages (from-to)	2708-2710
Number of pages	3
Journal	Inorganic Chemistry
Volume	48
Issue number	7
DOIs	https://doi.org/10.1021/ic8014578
State	Published - 2009

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic8014578

Cite this

@article{1b6a8e6270b246bdb97d90349cb15f42,

title = "Monomers and polymers of tripalladium(0) ditropylium halides",

abstract = "The synthesis and characterization of a series of polymeric complexes based upon a central tripalladium ditropylium (Tr) unit [Pd 3Tr 2] and containing different halide ligands are reported. The complexes were synthesized in good yield and characterized by multinuclei NMR spectroscopy, mass spectrometry, microanalysis, and X-ray crystallography. An unexpected product was an inorganic polymer consisting of linked individual tripalladium ditropylium units [Pd 3Tr 2X 2] ∞ (X = Cl, Br, and I); this is the first reported, crystallographically characterized example of polymeric tripalladium complexes with halide ligands.",

author = "Mulligan, \{Frank L.\} and Babbini, \{Dominic C.\} and Davis, \{Isaac R.\} and Hurst, \{Stephanie K.\} and Nichol, \{Gary S.\}",

year = "2009",

doi = "10.1021/ic8014578",

language = "English (US)",

volume = "48",

pages = "2708--2710",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - Monomers and polymers of tripalladium(0) ditropylium halides

AU - Mulligan, Frank L.

AU - Babbini, Dominic C.

AU - Davis, Isaac R.

AU - Hurst, Stephanie K.

AU - Nichol, Gary S.

PY - 2009

Y1 - 2009

N2 - The synthesis and characterization of a series of polymeric complexes based upon a central tripalladium ditropylium (Tr) unit [Pd 3Tr 2] and containing different halide ligands are reported. The complexes were synthesized in good yield and characterized by multinuclei NMR spectroscopy, mass spectrometry, microanalysis, and X-ray crystallography. An unexpected product was an inorganic polymer consisting of linked individual tripalladium ditropylium units [Pd 3Tr 2X 2] ∞ (X = Cl, Br, and I); this is the first reported, crystallographically characterized example of polymeric tripalladium complexes with halide ligands.

AB - The synthesis and characterization of a series of polymeric complexes based upon a central tripalladium ditropylium (Tr) unit [Pd 3Tr 2] and containing different halide ligands are reported. The complexes were synthesized in good yield and characterized by multinuclei NMR spectroscopy, mass spectrometry, microanalysis, and X-ray crystallography. An unexpected product was an inorganic polymer consisting of linked individual tripalladium ditropylium units [Pd 3Tr 2X 2] ∞ (X = Cl, Br, and I); this is the first reported, crystallographically characterized example of polymeric tripalladium complexes with halide ligands.

UR - https://www.scopus.com/pages/publications/64349124499

UR - https://www.scopus.com/pages/publications/64349124499#tab=citedBy

U2 - 10.1021/ic8014578

DO - 10.1021/ic8014578

M3 - Article

C2 - 19265425

AN - SCOPUS:64349124499

SN - 0020-1669

VL - 48

SP - 2708

EP - 2710

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 7

ER -

Monomers and polymers of tripalladium(0) ditropylium halides

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

CCDC 658437: Experimental Crystal Structure Determination

CCDC 693588: Experimental Crystal Structure Determination

CCDC 693587: Experimental Crystal Structure Determination

Cite this

Monomers and polymers of tripalladium(0) ditropylium halides

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 658437: Experimental Crystal Structure Determination

CCDC 693588: Experimental Crystal Structure Determination

CCDC 693587: Experimental Crystal Structure Determination

Cite this