Abstract
The synthesis and characterization of a series of polymeric complexes based upon a central tripalladium ditropylium (Tr) unit [Pd 3Tr 2] and containing different halide ligands are reported. The complexes were synthesized in good yield and characterized by multinuclei NMR spectroscopy, mass spectrometry, microanalysis, and X-ray crystallography. An unexpected product was an inorganic polymer consisting of linked individual tripalladium ditropylium units [Pd 3Tr 2X 2] ∞ (X = Cl, Br, and I); this is the first reported, crystallographically characterized example of polymeric tripalladium complexes with halide ligands.
Original language | English (US) |
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Pages (from-to) | 2708-2710 |
Number of pages | 3 |
Journal | Inorganic Chemistry |
Volume | 48 |
Issue number | 7 |
DOIs | |
State | Published - 2009 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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Dive into the research topics of 'Monomers and polymers of tripalladium(0) ditropylium halides'. Together they form a unique fingerprint.Datasets
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CCDC 658437: Experimental Crystal Structure Determination
Mulligan, F. L. (Creator), Babbini, D. C. (Creator), Davis, I. R. (Creator), Hurst, S. K. (Creator) & Nichol, G. S. (Creator), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccq34xv, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccq34xv&sid=DataCite
Dataset
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CCDC 693587: Experimental Crystal Structure Determination
Mulligan, F. L. (Creator), Babbini, D. C. (Creator), Davis, I. R. (Creator), Hurst, S. K. (Creator) & Nichol, G. S. (Creator), The Cambridge Structural Database, 2010
DOI: 10.5517/ccr8qsh, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccr8qsh&sid=DataCite
Dataset
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CCDC 693586: Experimental Crystal Structure Determination
Mulligan, F. L. (Creator), Babbini, D. C. (Creator), Davis, I. R. (Creator), Hurst, S. K. (Creator) & Nichol, G. S. (Creator), The Cambridge Structural Database, 2010
DOI: 10.5517/ccr8qrg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccr8qrg&sid=DataCite
Dataset