Miniature radiocarbon measurements (150gC) from sediments of Lake abińskie, Poland: Effect of precision and dating density on age-depth models

Paul D. Zander, Sönke Szidat, Darrell S. Kaufman, Maurycy Arczyński, Anna I. Poraj-Górska, Petra Boltshauser-Kaltenrieder, Martin Grosjean

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

The recent development of the MIni CArbon DAting System (MICADAS) allows researchers to obtain radiocarbon (14C) ages from a variety of samples with miniature amounts of carbon (<150ĝμgĝC) by using a gas ion source input that bypasses the graphitization step used for conventional 14C dating with accelerator mass spectrometry (AMS). The ability to measure smaller samples, at reduced cost compared with graphitized samples, allows for greater dating density of sediments with low macrofossil concentrations. In this study, we use a section of varved sediments from Lake abińskie, NE Poland, as a case study to assess the usefulness of miniature samples from terrestrial plant macrofossils for dating lake sediments. Radiocarbon samples analyzed using gas-source techniques were measured from the same depths as larger graphitized samples to compare the reliability and precision of the two techniques directly. We find that the analytical precision of gas-source measurements decreases as sample mass decreases but is comparable with graphitized samples of a similar size (approximately 150ĝμgĝC). For samples larger than 40ĝμgĝC and younger than 6000ĝBP, the uncalibrated 1σ age uncertainty is consistently less than 150 years (±0.010 F14C). The reliability of 14C ages from both techniques is assessed via comparison with a best-age estimate for the sediment sequence, which is the result of an OxCal V sequence that integrates varve counts with 14C ages. No bias is evident in the ages produced by either gas-source input or graphitization. None of the 14C ages in our dataset are clear outliers; the 95ĝ% confidence intervals of all 48 calibrated 14C ages overlap with the median best-age estimate. The effects of sample mass (which defines the expected analytical age uncertainty) and dating density on age-depth models are evaluated via simulated sets of 14C ages that are used as inputs for OxCal P-sequence age-depth models. Nine different sampling scenarios were simulated in which the mass of 14C samples and the number of samples were manipulated. The simulated age-depth models suggest that the lower analytical precision associated with miniature samples can be compensated for by increased dating density. The data presented in this paper can improve sampling strategies and can inform expectations of age uncertainty from miniature radiocarbon samples as well as age-depth model outcomes for lacustrine sediments.

Original languageEnglish (US)
Pages (from-to)63-79
Number of pages17
JournalGeochronology
Volume2
Issue number1
DOIs
StatePublished - Jan 24 2020
Externally publishedYes

ASJC Scopus subject areas

  • Stratigraphy
  • Palaeontology
  • Geology

Fingerprint

Dive into the research topics of 'Miniature radiocarbon measurements (150gC) from sediments of Lake abińskie, Poland: Effect of precision and dating density on age-depth models'. Together they form a unique fingerprint.

Cite this