Liquid-phase synthesis of thiol-derivatized silver nanocrystals

Srihari Murthy; Terry P. Bigioni; Z. L. Wang; Joseph T. Khoury; R. L. Whetten

doi:10.1016/S0167-577X(96)00274-1

Liquid-phase synthesis of thiol-derivatized silver nanocrystals

Srihari Murthy, Terry P. Bigioni, Z. L. Wang, Joseph T. Khoury, R. L. Whetten

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

A liquid-phase method is reported for the preparation of dodecanethiol-derivatized silver nanocrystals. Toluene sols of this material maintain as sols in air at room temperature at least on the timescale of months. X-ray diffraction (XRD) and transmission electron microscopy (TEM) are used to obtain size and structural information about the nanocrystal core while solubility properties and energy dispersive X-ray spectroscopy (EDS) are used to identify the passivating layer. Laser desorption time-of-flight mass spectra (LDTOFMS) of this material show broad peaks in the mass range from 40 to 300 kamu. These results are consistent with the synthesized material being a dodecanethiol-derivatized silver nanocrystal material with a mean crystalline silver core of 3.1 ± 0.6 nm.

Original language	English (US)
Pages (from-to)	321-325
Number of pages	5
Journal	Materials Letters
Volume	30
Issue number	4
DOIs	https://doi.org/10.1016/S0167-577X(96)00274-1
State	Published - Mar 1997
Externally published	Yes

Keywords

Nanoscale metal-organic composites
Self-assembled monolayers
Silver nanocrystals
TEM
Thiol-derivatization

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1016/S0167-577X(96)00274-1

Cite this

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title = "Liquid-phase synthesis of thiol-derivatized silver nanocrystals",

abstract = "A liquid-phase method is reported for the preparation of dodecanethiol-derivatized silver nanocrystals. Toluene sols of this material maintain as sols in air at room temperature at least on the timescale of months. X-ray diffraction (XRD) and transmission electron microscopy (TEM) are used to obtain size and structural information about the nanocrystal core while solubility properties and energy dispersive X-ray spectroscopy (EDS) are used to identify the passivating layer. Laser desorption time-of-flight mass spectra (LDTOFMS) of this material show broad peaks in the mass range from 40 to 300 kamu. These results are consistent with the synthesized material being a dodecanethiol-derivatized silver nanocrystal material with a mean crystalline silver core of 3.1 ± 0.6 nm.",

keywords = "Nanoscale metal-organic composites, Self-assembled monolayers, Silver nanocrystals, TEM, Thiol-derivatization",

author = "Srihari Murthy and Bigioni, \{Terry P.\} and Wang, \{Z. L.\} and Khoury, \{Joseph T.\} and Whetten, \{R. L.\}",

year = "1997",

month = mar,

doi = "10.1016/S0167-577X(96)00274-1",

language = "English (US)",

volume = "30",

pages = "321--325",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier B.V.",

number = "4",

}

TY - JOUR

T1 - Liquid-phase synthesis of thiol-derivatized silver nanocrystals

AU - Murthy, Srihari

AU - Bigioni, Terry P.

AU - Wang, Z. L.

AU - Khoury, Joseph T.

AU - Whetten, R. L.

PY - 1997/3

Y1 - 1997/3

N2 - A liquid-phase method is reported for the preparation of dodecanethiol-derivatized silver nanocrystals. Toluene sols of this material maintain as sols in air at room temperature at least on the timescale of months. X-ray diffraction (XRD) and transmission electron microscopy (TEM) are used to obtain size and structural information about the nanocrystal core while solubility properties and energy dispersive X-ray spectroscopy (EDS) are used to identify the passivating layer. Laser desorption time-of-flight mass spectra (LDTOFMS) of this material show broad peaks in the mass range from 40 to 300 kamu. These results are consistent with the synthesized material being a dodecanethiol-derivatized silver nanocrystal material with a mean crystalline silver core of 3.1 ± 0.6 nm.

AB - A liquid-phase method is reported for the preparation of dodecanethiol-derivatized silver nanocrystals. Toluene sols of this material maintain as sols in air at room temperature at least on the timescale of months. X-ray diffraction (XRD) and transmission electron microscopy (TEM) are used to obtain size and structural information about the nanocrystal core while solubility properties and energy dispersive X-ray spectroscopy (EDS) are used to identify the passivating layer. Laser desorption time-of-flight mass spectra (LDTOFMS) of this material show broad peaks in the mass range from 40 to 300 kamu. These results are consistent with the synthesized material being a dodecanethiol-derivatized silver nanocrystal material with a mean crystalline silver core of 3.1 ± 0.6 nm.

KW - Nanoscale metal-organic composites

KW - Self-assembled monolayers

KW - Silver nanocrystals

KW - TEM

KW - Thiol-derivatization

UR - https://www.scopus.com/pages/publications/0031098392

UR - https://www.scopus.com/inward/citedby.url?scp=0031098392&partnerID=8YFLogxK

U2 - 10.1016/S0167-577X(96)00274-1

DO - 10.1016/S0167-577X(96)00274-1

M3 - Article

AN - SCOPUS:0031098392

SN - 0167-577X

VL - 30

SP - 321

EP - 325

JO - Materials Letters

JF - Materials Letters

IS - 4

ER -

Liquid-phase synthesis of thiol-derivatized silver nanocrystals

Abstract

Keywords

ASJC Scopus subject areas

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