La2C80: A soluble dimetallofullerene

Marcos M. Alvarez, Edward G. Gillan, Károly Holczer, Richard B. Kaner, Kyu S. Min, Robert L. Whetten

Research output: Contribution to journalArticlepeer-review

191 Scopus citations

Abstract

Application of the Krätschmer-Huffman method to a lanthana-graphite mixture yields an extractable molecule of formula La2C80, in addition to the recently reported LaC82. Its solubility properties suggest that it is similar to the well-characterized higher fullerenes C76, C78, and C84, and its estimated yield, based on laser-desorption mass spectra of (±)-charged molecules, is comparable to these. The finding of a series of particularly extractable molecules (LanC84-2n, n = 0, 1, 2) could indicate either a special type of structure or an isoelectronic series. We are attempting to isolate this molecule by chromatography.

Original languageEnglish (US)
Pages (from-to)10561-10563
Number of pages3
JournalJournal of physical chemistry
Volume95
Issue number26
DOIs
StatePublished - 1991
Externally publishedYes

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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