Infrared spectra and band strengths of amorphous and crystalline N2O

R. L. Hudson, M. J. Loeffler, P. A. Gerakines

Research output: Contribution to journalArticlepeer-review

27 Scopus citations

Abstract

Infrared transmission spectra from 4000 to 400 cm−1, and associated band strengths and absorption coefficients, are presented for the first time for both amorphous and crystalline N2O. Changes in the spectra as a function of ice thickness and ice temperature are shown. New measurements of density, refractive index, and specific refraction are reported for amorphous and crystalline N2O. Comparisons are made to published results, and the most-likely reason for some recent disagreements in the literature is discussed. As with CO2, its isoelectronic congener, the formation of amorphous N2O is found to require greater care than the formation of amorphous solids from more-polar molecules.

Original languageEnglish (US)
Article number024304
JournalJournal of Chemical Physics
Volume146
Issue number2
DOIs
StatePublished - Jan 14 2017
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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