Fully Cationized Gold Clusters: Synthesis of Au25(SR+)18

Yohei Ishida; Kunihiro Narita; Tetsu Yonezawa; Robert L. Whetten

doi:10.1021/acs.jpclett.6b01725

Fully Cationized Gold Clusters: Synthesis of Au₂₅(SR⁺)₁₈

Yohei Ishida, Kunihiro Narita, Tetsu Yonezawa, Robert L. Whetten

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Although many thiolate-protected Au clusters with different numbers of Au atoms and a variety of thiolate ligands have been synthesized, to date there has been no report of a fully cationized Au cluster protected with cationic thiolates. Herein, we report the synthesis of the first member of a new series of thiolate-protected Au cluster molecules: a fully cationized Au₂₅(SR⁺)₁₈ cluster.

Original language	English (US)
Pages (from-to)	3718-3722
Number of pages	5
Journal	Journal of Physical Chemistry Letters
Volume	7
Issue number	19
DOIs	https://doi.org/10.1021/acs.jpclett.6b01725
State	Published - Oct 6 2016
Externally published	Yes

ASJC Scopus subject areas

General Materials Science
Physical and Theoretical Chemistry

Access to Document

10.1021/acs.jpclett.6b01725

Cite this

@article{6104318a834e4767b7579128a97cf000,

title = "Fully Cationized Gold Clusters: Synthesis of Au25(SR+)18",

abstract = "Although many thiolate-protected Au clusters with different numbers of Au atoms and a variety of thiolate ligands have been synthesized, to date there has been no report of a fully cationized Au cluster protected with cationic thiolates. Herein, we report the synthesis of the first member of a new series of thiolate-protected Au cluster molecules: a fully cationized Au25(SR+)18 cluster.",

author = "Yohei Ishida and Kunihiro Narita and Tetsu Yonezawa and Whetten, \{Robert L.\}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = oct,

day = "6",

doi = "10.1021/acs.jpclett.6b01725",

language = "English (US)",

volume = "7",

pages = "3718--3722",

journal = "Journal of Physical Chemistry Letters",

issn = "1948-7185",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - Fully Cationized Gold Clusters

T2 - Synthesis of Au25(SR+)18

AU - Ishida, Yohei

AU - Narita, Kunihiro

AU - Yonezawa, Tetsu

AU - Whetten, Robert L.

PY - 2016/10/6

Y1 - 2016/10/6

N2 - Although many thiolate-protected Au clusters with different numbers of Au atoms and a variety of thiolate ligands have been synthesized, to date there has been no report of a fully cationized Au cluster protected with cationic thiolates. Herein, we report the synthesis of the first member of a new series of thiolate-protected Au cluster molecules: a fully cationized Au25(SR+)18 cluster.

AB - Although many thiolate-protected Au clusters with different numbers of Au atoms and a variety of thiolate ligands have been synthesized, to date there has been no report of a fully cationized Au cluster protected with cationic thiolates. Herein, we report the synthesis of the first member of a new series of thiolate-protected Au cluster molecules: a fully cationized Au25(SR+)18 cluster.

UR - https://www.scopus.com/pages/publications/84990055822

UR - https://www.scopus.com/inward/citedby.url?scp=84990055822&partnerID=8YFLogxK

U2 - 10.1021/acs.jpclett.6b01725

DO - 10.1021/acs.jpclett.6b01725

M3 - Article

AN - SCOPUS:84990055822

SN - 1948-7185

VL - 7

SP - 3718

EP - 3722

JO - Journal of Physical Chemistry Letters

JF - Journal of Physical Chemistry Letters

IS - 19

ER -

Fully Cationized Gold Clusters: Synthesis of Au₂₅(SR⁺)₁₈

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this