Fully Cationized Gold Clusters: Synthesis of Au25(SR+)18

Yohei Ishida, Kunihiro Narita, Tetsu Yonezawa, Robert L. Whetten

Research output: Contribution to journalArticlepeer-review

31 Scopus citations

Abstract

Although many thiolate-protected Au clusters with different numbers of Au atoms and a variety of thiolate ligands have been synthesized, to date there has been no report of a fully cationized Au cluster protected with cationic thiolates. Herein, we report the synthesis of the first member of a new series of thiolate-protected Au cluster molecules: a fully cationized Au25(SR+)18 cluster.

Original languageEnglish (US)
Pages (from-to)3718-3722
Number of pages5
JournalJournal of Physical Chemistry Letters
Volume7
Issue number19
DOIs
StatePublished - Oct 6 2016
Externally publishedYes

ASJC Scopus subject areas

  • Materials Science(all)
  • Physical and Theoretical Chemistry

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