Fullerene isomerism: Isolation of C2v-C78 and D 3-C78

François Diederich, Robert L. Whetten, Carlo Thilgen, Roland Ettl, Ito Chao, Marcos M. Alvarez

Research output: Contribution to journalArticlepeer-review

368 Scopus citations

Abstract

Early reports on the formation of the higher fullerenes C76, C78, C84, C90, and C94 by resistive heating of graphite stimulated theoretical calculations of possible cage structures for these all-carbon molecules. Among the five fullerene structures with isolated pentagons found for C78, a closed-shell D 3h-isomer was predicted to form preferentially. Two distinct C 78-isomers were formed in a ratio of ∼5:1 and could be separated by high-performance liquid chromatography. The carbon-13 nuclear magnetic resonance (NMR) spectrum of the major isomer is uniquely consistent with a C2v-structure. The NMR data also support a chiral D 3-structure for the minor isomer. The isolation of specifically these two isomers of C78 provides insight into the stability of higher fullerene structures and into the mechanism for fullerene formation in general.

Original languageEnglish (US)
Pages (from-to)1768-1770
Number of pages3
JournalScience
Volume254
Issue number5039
DOIs
StatePublished - 1991
Externally publishedYes

ASJC Scopus subject areas

  • General

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