Fractional quantization of molecular pseudorotation in Na3

Guy Delacrétaz; Edward R. Grant; Robert L. Whetten; Ludger Wöste; Josef W. Zwanziger

doi:10.1103/PhysRevLett.56.2598

Fractional quantization of molecular pseudorotation in Na3

Guy Delacrétaz, Edward R. Grant, Robert L. Whetten, Ludger Wöste, Josef W. Zwanziger

Research output: Contribution to journal › Article › peer-review

291 Scopus citations

Abstract

Fractional quantization of the adiabatic pseudorotation in an isolated molecule is reported. This result, concerning the large-amplitude pseudorotation in 22E Na3, constitutes the first direct verification of the adiabatic sign-change theorem, and also presents the most complete picture of the level structure and internuclear dynamics of a metal-atom cluster yet given.

Original language	English (US)
Pages (from-to)	2598-2601
Number of pages	4
Journal	Physical Review Letters
Volume	56
Issue number	24
DOIs	https://doi.org/10.1103/PhysRevLett.56.2598
State	Published - 1986
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy

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10.1103/PhysRevLett.56.2598

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title = "Fractional quantization of molecular pseudorotation in Na3",

abstract = "Fractional quantization of the adiabatic pseudorotation in an isolated molecule is reported. This result, concerning the large-amplitude pseudorotation in 22E Na3, constitutes the first direct verification of the adiabatic sign-change theorem, and also presents the most complete picture of the level structure and internuclear dynamics of a metal-atom cluster yet given.",

author = "Guy Delacr{\'e}taz and Grant, \{Edward R.\} and Whetten, \{Robert L.\} and Ludger W{\"o}ste and Zwanziger, \{Josef W.\}",

year = "1986",

doi = "10.1103/PhysRevLett.56.2598",

language = "English (US)",

volume = "56",

pages = "2598--2601",

journal = "Physical Review Letters",

issn = "0031-9007",

publisher = "American Physical Society",

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AU - Delacrétaz, Guy

AU - Grant, Edward R.

AU - Whetten, Robert L.

AU - Wöste, Ludger

AU - Zwanziger, Josef W.

PY - 1986

Y1 - 1986

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AB - Fractional quantization of the adiabatic pseudorotation in an isolated molecule is reported. This result, concerning the large-amplitude pseudorotation in 22E Na3, constitutes the first direct verification of the adiabatic sign-change theorem, and also presents the most complete picture of the level structure and internuclear dynamics of a metal-atom cluster yet given.

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DO - 10.1103/PhysRevLett.56.2598

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Fractional quantization of molecular pseudorotation in Na3

Abstract

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