Fabrication of magnetic functionalised calix[4]arene composite for highly efficient and selective adsorption towards uranium(VI)

Fang Zhu Xiao; Cheng Wang; Li Mei Yu; Yi Qiu Pu; Yu Li Xu; Kang Zhang; Jia Qi Luo; Qi Qi Zhu; Fang Chen; Yong Liu; Chun Hsing Ho; Guo Wen Peng; Shu Ya He

doi:10.1071/EN19014

Fabrication of magnetic functionalised calix[4]arene composite for highly efficient and selective adsorption towards uranium(VI)

Fang Zhu Xiao
, Cheng Wang
, Li Mei Yu
, Yi Qiu Pu
, Yu Li Xu
, Kang Zhang
, Jia Qi Luo
, Qi Qi Zhu
, Fang Chen
, Yong Liu
, Chun Hsing Ho
, Guo Wen Peng
, Shu Ya He

Civil Engineering, Construction Management, and Environmental Engineering

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A magnetic functionalised calix[4]arene composite consisting of Fe₃O₄ and calix[4]arene phosphonate derivative (CPD) was prepared through a facile self-assembly method. The composite was characterised by scanning electron microscopy (SEM), powder X-ray diffraction (PXRD) and Fourier transform infrared spectroscopy (FTIR). The as-synthesised Fe₃O₄/CPD composite was used to remove U^VI from aqueous solutions under different conditions. Meanwhile, the adsorption isotherm, kinetics and thermodynamics were fitted and analysed. The results show that the Fe₃O₄/CPD composite may be a promising adsorption material for the separation and enrichment of U^VI from aqueous solutions in the cleanup of environmental pollution.

Original language	English (US)
Pages (from-to)	577-586
Number of pages	10
Journal	Environmental Chemistry
Volume	16
Issue number	8
DOIs	https://doi.org/10.1071/EN19014
State	Published - 2019

Keywords

FeO
calixarene
magnetic materials
separation

ASJC Scopus subject areas

Chemistry (miscellaneous)
Environmental Chemistry
Geochemistry and Petrology

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10.1071/EN19014

Cite this

@article{383ea52f55ed48349fb8dd241bc16177,

title = "Fabrication of magnetic functionalised calix[4]arene composite for highly efficient and selective adsorption towards uranium(VI)",

abstract = "A magnetic functionalised calix[4]arene composite consisting of Fe3O4 and calix[4]arene phosphonate derivative (CPD) was prepared through a facile self-assembly method. The composite was characterised by scanning electron microscopy (SEM), powder X-ray diffraction (PXRD) and Fourier transform infrared spectroscopy (FTIR). The as-synthesised Fe3O4/CPD composite was used to remove UVI from aqueous solutions under different conditions. Meanwhile, the adsorption isotherm, kinetics and thermodynamics were fitted and analysed. The results show that the Fe3O4/CPD composite may be a promising adsorption material for the separation and enrichment of UVI from aqueous solutions in the cleanup of environmental pollution.",

keywords = "FeO, calixarene, magnetic materials, separation",

author = "Xiao, \{Fang Zhu\} and Cheng Wang and Yu, \{Li Mei\} and Pu, \{Yi Qiu\} and Xu, \{Yu Li\} and Kang Zhang and Luo, \{Jia Qi\} and Zhu, \{Qi Qi\} and Fang Chen and Yong Liu and Ho, \{Chun Hsing\} and Peng, \{Guo Wen\} and He, \{Shu Ya\}",

note = "Publisher Copyright: {\textcopyright} 2019 CSIRO.",

year = "2019",

doi = "10.1071/EN19014",

language = "English (US)",

volume = "16",

pages = "577--586",

journal = "Environmental Chemistry",

issn = "1448-2517",

publisher = "CSIRO Publishing ",

number = "8",

}

TY - JOUR

T1 - Fabrication of magnetic functionalised calix[4]arene composite for highly efficient and selective adsorption towards uranium(VI)

AU - Xiao, Fang Zhu

AU - Wang, Cheng

AU - Yu, Li Mei

AU - Pu, Yi Qiu

AU - Xu, Yu Li

AU - Zhang, Kang

AU - Luo, Jia Qi

AU - Zhu, Qi Qi

AU - Chen, Fang

AU - Liu, Yong

AU - Ho, Chun Hsing

AU - Peng, Guo Wen

AU - He, Shu Ya

PY - 2019

Y1 - 2019

N2 - A magnetic functionalised calix[4]arene composite consisting of Fe3O4 and calix[4]arene phosphonate derivative (CPD) was prepared through a facile self-assembly method. The composite was characterised by scanning electron microscopy (SEM), powder X-ray diffraction (PXRD) and Fourier transform infrared spectroscopy (FTIR). The as-synthesised Fe3O4/CPD composite was used to remove UVI from aqueous solutions under different conditions. Meanwhile, the adsorption isotherm, kinetics and thermodynamics were fitted and analysed. The results show that the Fe3O4/CPD composite may be a promising adsorption material for the separation and enrichment of UVI from aqueous solutions in the cleanup of environmental pollution.

AB - A magnetic functionalised calix[4]arene composite consisting of Fe3O4 and calix[4]arene phosphonate derivative (CPD) was prepared through a facile self-assembly method. The composite was characterised by scanning electron microscopy (SEM), powder X-ray diffraction (PXRD) and Fourier transform infrared spectroscopy (FTIR). The as-synthesised Fe3O4/CPD composite was used to remove UVI from aqueous solutions under different conditions. Meanwhile, the adsorption isotherm, kinetics and thermodynamics were fitted and analysed. The results show that the Fe3O4/CPD composite may be a promising adsorption material for the separation and enrichment of UVI from aqueous solutions in the cleanup of environmental pollution.

KW - FeO

KW - calixarene

KW - magnetic materials

KW - separation

UR - https://www.scopus.com/pages/publications/85066465675

UR - https://www.scopus.com/pages/publications/85066465675#tab=citedBy

U2 - 10.1071/EN19014

DO - 10.1071/EN19014

M3 - Article

AN - SCOPUS:85066465675

SN - 1448-2517

VL - 16

SP - 577

EP - 586

JO - Environmental Chemistry

JF - Environmental Chemistry

IS - 8

ER -

Fabrication of magnetic functionalised calix[4]arene composite for highly efficient and selective adsorption towards uranium(VI)

Abstract

Keywords

ASJC Scopus subject areas

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