Electrical conductance and ultrasonic relaxation for lithium perchlorate in tetrahydrofuran

Paul Jagodzinski; Sergio Petrucci

doi:10.1021/j100602a013

Electrical conductance and ultrasonic relaxation for lithium perchlorate in tetrahydrofuran

Paul Jagodzinski, Sergio Petrucci

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Electrical conductance (10^-5 to 1 M) at 25, -15, and -30° and ultrasonic absorption (0.05-0.5 M) in the frequency range 5-330 MHz at 25, -15, and -30° have been measured for LiClO₄ in tetrahydrofuran (THF). The electrical conductance data reveal the presence of a minimum that can be interpreted and evaluated by the Fuoss-Kraus theory of triple ion formation (up to ∼0.1 M). Numerical evaluation of ion pair and triple ion pair constants were made. The ultrasonic relaxation data are interpreted as due to the process of formation of triple ions, the barrier of activation energy for the process being comparable to the one for viscous flow.

Original language	English (US)
Pages (from-to)	917-925
Number of pages	9
Journal	Journal of physical chemistry
Volume	78
Issue number	9
DOIs	https://doi.org/10.1021/j100602a013
State	Published - 1974
Externally published	Yes

ASJC Scopus subject areas

General Engineering
Physical and Theoretical Chemistry

Access to Document

10.1021/j100602a013

Cite this

@article{9fe71c7cc54748aeacc714a40676df87,

title = "Electrical conductance and ultrasonic relaxation for lithium perchlorate in tetrahydrofuran",

abstract = "Electrical conductance (10-5 to 1 M) at 25, -15, and -30° and ultrasonic absorption (0.05-0.5 M) in the frequency range 5-330 MHz at 25, -15, and -30° have been measured for LiClO4 in tetrahydrofuran (THF). The electrical conductance data reveal the presence of a minimum that can be interpreted and evaluated by the Fuoss-Kraus theory of triple ion formation (up to ∼0.1 M). Numerical evaluation of ion pair and triple ion pair constants were made. The ultrasonic relaxation data are interpreted as due to the process of formation of triple ions, the barrier of activation energy for the process being comparable to the one for viscous flow.",

author = "Paul Jagodzinski and Sergio Petrucci",

year = "1974",

doi = "10.1021/j100602a013",

language = "English (US)",

volume = "78",

pages = "917--925",

journal = "Journal of physical chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Electrical conductance and ultrasonic relaxation for lithium perchlorate in tetrahydrofuran

AU - Jagodzinski, Paul

AU - Petrucci, Sergio

PY - 1974

Y1 - 1974

N2 - Electrical conductance (10-5 to 1 M) at 25, -15, and -30° and ultrasonic absorption (0.05-0.5 M) in the frequency range 5-330 MHz at 25, -15, and -30° have been measured for LiClO4 in tetrahydrofuran (THF). The electrical conductance data reveal the presence of a minimum that can be interpreted and evaluated by the Fuoss-Kraus theory of triple ion formation (up to ∼0.1 M). Numerical evaluation of ion pair and triple ion pair constants were made. The ultrasonic relaxation data are interpreted as due to the process of formation of triple ions, the barrier of activation energy for the process being comparable to the one for viscous flow.

AB - Electrical conductance (10-5 to 1 M) at 25, -15, and -30° and ultrasonic absorption (0.05-0.5 M) in the frequency range 5-330 MHz at 25, -15, and -30° have been measured for LiClO4 in tetrahydrofuran (THF). The electrical conductance data reveal the presence of a minimum that can be interpreted and evaluated by the Fuoss-Kraus theory of triple ion formation (up to ∼0.1 M). Numerical evaluation of ion pair and triple ion pair constants were made. The ultrasonic relaxation data are interpreted as due to the process of formation of triple ions, the barrier of activation energy for the process being comparable to the one for viscous flow.

UR - http://www.scopus.com/inward/record.url?scp=0001162920&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001162920&partnerID=8YFLogxK

U2 - 10.1021/j100602a013

DO - 10.1021/j100602a013

M3 - Article

AN - SCOPUS:0001162920

SN - 0022-3654

VL - 78

SP - 917

EP - 925

JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 9

ER -

Electrical conductance and ultrasonic relaxation for lithium perchlorate in tetrahydrofuran

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this