Distillation kinetics of solid mixtures of hydrogen peroxide and water and the isolation of pure hydrogen peroxide in ultrahigh vacuum

M. J. Loeffler; B. D. Teolis; R. A. Baragiola

doi:10.1021/jp060289s

Distillation kinetics of solid mixtures of hydrogen peroxide and water and the isolation of pure hydrogen peroxide in ultrahigh vacuum

M. J. Loeffler, B. D. Teolis, R. A. Baragiola

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

We present results of the growth of thin films of crystalline H ₂O₂ and H₂O₂·2H ₂O₂ (dihydrate) in ultrahigh vacuum by distilling an aqueous solution of hydrogen peroxide. We traced the process using infrared reflectance spectroscopy, mass loss on a quartz crystal microbalance, and in a few cases ultraviolet-visible reflectance. We find that the different crystalline phases-water, dihydrate, and hydrogen peroxide-have very different sublimation rates, making distillation efficient to isolate the less volatile component, crystalline H₂O₂.

Original language	English (US)
Pages (from-to)	6911-6915
Number of pages	5
Journal	Journal of Physical Chemistry B
Volume	110
Issue number	13
DOIs	https://doi.org/10.1021/jp060289s
State	Published - May 6 2006
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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abstract = "We present results of the growth of thin films of crystalline H 2O2 and H2O2·2H 2O2 (dihydrate) in ultrahigh vacuum by distilling an aqueous solution of hydrogen peroxide. We traced the process using infrared reflectance spectroscopy, mass loss on a quartz crystal microbalance, and in a few cases ultraviolet-visible reflectance. We find that the different crystalline phases-water, dihydrate, and hydrogen peroxide-have very different sublimation rates, making distillation efficient to isolate the less volatile component, crystalline H2O2.",

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T1 - Distillation kinetics of solid mixtures of hydrogen peroxide and water and the isolation of pure hydrogen peroxide in ultrahigh vacuum

AU - Loeffler, M. J.

AU - Teolis, B. D.

AU - Baragiola, R. A.

PY - 2006/5/6

Y1 - 2006/5/6

N2 - We present results of the growth of thin films of crystalline H 2O2 and H2O2·2H 2O2 (dihydrate) in ultrahigh vacuum by distilling an aqueous solution of hydrogen peroxide. We traced the process using infrared reflectance spectroscopy, mass loss on a quartz crystal microbalance, and in a few cases ultraviolet-visible reflectance. We find that the different crystalline phases-water, dihydrate, and hydrogen peroxide-have very different sublimation rates, making distillation efficient to isolate the less volatile component, crystalline H2O2.

AB - We present results of the growth of thin films of crystalline H 2O2 and H2O2·2H 2O2 (dihydrate) in ultrahigh vacuum by distilling an aqueous solution of hydrogen peroxide. We traced the process using infrared reflectance spectroscopy, mass loss on a quartz crystal microbalance, and in a few cases ultraviolet-visible reflectance. We find that the different crystalline phases-water, dihydrate, and hydrogen peroxide-have very different sublimation rates, making distillation efficient to isolate the less volatile component, crystalline H2O2.

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Distillation kinetics of solid mixtures of hydrogen peroxide and water and the isolation of pure hydrogen peroxide in ultrahigh vacuum

Abstract

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