Diblock Copolymer Micelles and Supported Films with Noncovalently Incorporated Chromophores: A Modular Platform for Efficient Energy Transfer

Peter G. Adams; Aaron M. Collins; Tuba Sahin; Vijaya Subramanian; Volker S. Urban; Pothiappan Vairaprakash; Yongming Tian; Deborah G. Evans; Andrew P. Shreve; Gabriel A. Montaño

doi:10.1021/nl504814x

Diblock Copolymer Micelles and Supported Films with Noncovalently Incorporated Chromophores: A Modular Platform for Efficient Energy Transfer

Peter G. Adams, Aaron M. Collins, Tuba Sahin, Vijaya Subramanian, Volker S. Urban, Pothiappan Vairaprakash, Yongming Tian, Deborah G. Evans, Andrew P. Shreve, Gabriel A. Montaño

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

We report generation of modular, artificial light-harvesting assemblies where an amphiphilic diblock copolymer, poly(ethylene oxide)-block-poly(butadiene), serves as the framework for noncovalent organization of BODIPY-based energy donor and bacteriochlorin-based energy acceptor chromophores. The assemblies are adaptive and form well-defined micelles in aqueous solution and high-quality monolayer and bilayer films on solid supports, with the latter showing greater than 90% energy transfer efficiency. This study lays the groundwork for further development of modular, polymer-based materials for light harvesting and other photonic applications. (Graph Presented).

Original language	English (US)
Pages (from-to)	2422-2428
Number of pages	7
Journal	Nano Letters
Volume	15
Issue number	4
DOIs	https://doi.org/10.1021/nl504814x
State	Published - Apr 8 2015
Externally published	Yes

Keywords

Amphiphilic diblock copolymers
Artificial light harvesting
Förster resonance energy transfer

ASJC Scopus subject areas

Bioengineering
General Chemistry
General Materials Science
Condensed Matter Physics
Mechanical Engineering

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10.1021/nl504814x

Cite this

@article{8932cd44c983431aadbb7388102b0ef9,

title = "Diblock Copolymer Micelles and Supported Films with Noncovalently Incorporated Chromophores: A Modular Platform for Efficient Energy Transfer",

abstract = "We report generation of modular, artificial light-harvesting assemblies where an amphiphilic diblock copolymer, poly(ethylene oxide)-block-poly(butadiene), serves as the framework for noncovalent organization of BODIPY-based energy donor and bacteriochlorin-based energy acceptor chromophores. The assemblies are adaptive and form well-defined micelles in aqueous solution and high-quality monolayer and bilayer films on solid supports, with the latter showing greater than 90\% energy transfer efficiency. This study lays the groundwork for further development of modular, polymer-based materials for light harvesting and other photonic applications. (Graph Presented).",

keywords = "Amphiphilic diblock copolymers, Artificial light harvesting, F{\"o}rster resonance energy transfer",

author = "Adams, \{Peter G.\} and Collins, \{Aaron M.\} and Tuba Sahin and Vijaya Subramanian and Urban, \{Volker S.\} and Pothiappan Vairaprakash and Yongming Tian and Evans, \{Deborah G.\} and Shreve, \{Andrew P.\} and Monta{\~n}o, \{Gabriel A.\}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = apr,

day = "8",

doi = "10.1021/nl504814x",

language = "English (US)",

volume = "15",

pages = "2422--2428",

journal = "Nano Letters",

issn = "1530-6984",

publisher = "American Chemical Society",

number = "4",

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TY - JOUR

T1 - Diblock Copolymer Micelles and Supported Films with Noncovalently Incorporated Chromophores

T2 - A Modular Platform for Efficient Energy Transfer

AU - Adams, Peter G.

AU - Collins, Aaron M.

AU - Sahin, Tuba

AU - Subramanian, Vijaya

AU - Urban, Volker S.

AU - Vairaprakash, Pothiappan

AU - Tian, Yongming

AU - Evans, Deborah G.

AU - Shreve, Andrew P.

AU - Montaño, Gabriel A.

PY - 2015/4/8

Y1 - 2015/4/8

N2 - We report generation of modular, artificial light-harvesting assemblies where an amphiphilic diblock copolymer, poly(ethylene oxide)-block-poly(butadiene), serves as the framework for noncovalent organization of BODIPY-based energy donor and bacteriochlorin-based energy acceptor chromophores. The assemblies are adaptive and form well-defined micelles in aqueous solution and high-quality monolayer and bilayer films on solid supports, with the latter showing greater than 90% energy transfer efficiency. This study lays the groundwork for further development of modular, polymer-based materials for light harvesting and other photonic applications. (Graph Presented).

AB - We report generation of modular, artificial light-harvesting assemblies where an amphiphilic diblock copolymer, poly(ethylene oxide)-block-poly(butadiene), serves as the framework for noncovalent organization of BODIPY-based energy donor and bacteriochlorin-based energy acceptor chromophores. The assemblies are adaptive and form well-defined micelles in aqueous solution and high-quality monolayer and bilayer films on solid supports, with the latter showing greater than 90% energy transfer efficiency. This study lays the groundwork for further development of modular, polymer-based materials for light harvesting and other photonic applications. (Graph Presented).

KW - Amphiphilic diblock copolymers

KW - Artificial light harvesting

KW - Förster resonance energy transfer

UR - https://www.scopus.com/pages/publications/84926636897

UR - https://www.scopus.com/inward/citedby.url?scp=84926636897&partnerID=8YFLogxK

U2 - 10.1021/nl504814x

DO - 10.1021/nl504814x

M3 - Article

AN - SCOPUS:84926636897

SN - 1530-6984

VL - 15

SP - 2422

EP - 2428

JO - Nano Letters

JF - Nano Letters

IS - 4

ER -

Diblock Copolymer Micelles and Supported Films with Noncovalently Incorporated Chromophores: A Modular Platform for Efficient Energy Transfer

Abstract

Keywords

ASJC Scopus subject areas

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