Determination of the specific activity for methylcyclohexane dehydrogenation of different surface orientations of palladium-supported catalysts

A. Corma; M. A. Martin; J. A. Pajares; J. Perez-Pariente; M. Avalos; M. Jose Yacaman

doi:10.1016/0304-5102(88)85005-3

Determination of the specific activity for methylcyclohexane dehydrogenation of different surface orientations of palladium-supported catalysts

A. Corma, M. A. Martin, J. A. Pajares, J. Perez-Pariente, M. Avalos, M. Jose Yacaman

Research output: Contribution to journal › Article › peer-review

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Abstract

The percentage of crystallites with different plane orientations (111), (110), (100) on a Pd-supported catalyst has been measured using TEM and chemisorption of O₂, H₂ and CO. Specific catalytic activities of the different crystal faces have been determined for the dehydrogenation of methylcyclohexane. It is found that the (111) face is four times more active than either the (110) or (100) face.

Original language	English (US)
Pages (from-to)	199-205
Number of pages	7
Journal	Journal of Molecular Catalysis
Volume	48
Issue number	2-3
DOIs	https://doi.org/10.1016/0304-5102(88)85005-3
State	Published - Nov 21 1988
Externally published	Yes

ASJC Scopus subject areas

General Engineering

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10.1016/0304-5102(88)85005-3

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title = "Determination of the specific activity for methylcyclohexane dehydrogenation of different surface orientations of palladium-supported catalysts",

abstract = "The percentage of crystallites with different plane orientations (111), (110), (100) on a Pd-supported catalyst has been measured using TEM and chemisorption of O2, H2 and CO. Specific catalytic activities of the different crystal faces have been determined for the dehydrogenation of methylcyclohexane. It is found that the (111) face is four times more active than either the (110) or (100) face.",

author = "A. Corma and Martin, {M. A.} and Pajares, {J. A.} and J. Perez-Pariente and M. Avalos and Yacaman, {M. Jose}",

note = "Funding Information: The authors are indebted to Mr. Fco. Ruiz, R. Hemandez, Samuel Tehuacanero and J. Reyes-Casca for technical help with the electron microscopy and image processing. This work was partially supported by the Convenio Hispano-Mexican0 de Colaboracion Cientifica, and by the CAICYT 6131183.",

year = "1988",

month = nov,

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doi = "10.1016/0304-5102(88)85005-3",

language = "English (US)",

volume = "48",

pages = "199--205",

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TY - JOUR

T1 - Determination of the specific activity for methylcyclohexane dehydrogenation of different surface orientations of palladium-supported catalysts

AU - Corma, A.

AU - Martin, M. A.

AU - Pajares, J. A.

AU - Perez-Pariente, J.

AU - Avalos, M.

AU - Yacaman, M. Jose

N1 - Funding Information: The authors are indebted to Mr. Fco. Ruiz, R. Hemandez, Samuel Tehuacanero and J. Reyes-Casca for technical help with the electron microscopy and image processing. This work was partially supported by the Convenio Hispano-Mexican0 de Colaboracion Cientifica, and by the CAICYT 6131183.

PY - 1988/11/21

Y1 - 1988/11/21

N2 - The percentage of crystallites with different plane orientations (111), (110), (100) on a Pd-supported catalyst has been measured using TEM and chemisorption of O2, H2 and CO. Specific catalytic activities of the different crystal faces have been determined for the dehydrogenation of methylcyclohexane. It is found that the (111) face is four times more active than either the (110) or (100) face.

AB - The percentage of crystallites with different plane orientations (111), (110), (100) on a Pd-supported catalyst has been measured using TEM and chemisorption of O2, H2 and CO. Specific catalytic activities of the different crystal faces have been determined for the dehydrogenation of methylcyclohexane. It is found that the (111) face is four times more active than either the (110) or (100) face.

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U2 - 10.1016/0304-5102(88)85005-3

DO - 10.1016/0304-5102(88)85005-3

M3 - Article

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VL - 48

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EP - 205

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

IS - 2-3

ER -

Determination of the specific activity for methylcyclohexane dehydrogenation of different surface orientations of palladium-supported catalysts

Abstract

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