Crystal structure, physical properties and Pt-195 NMR characterization of Pt(bipy)Br2

David A. Sartori; Stephanie K. Hurst; Nathan Wood; Raymond D. Larsen; Edwin H. Abbott

doi:10.1007/s10870-005-5837-x

Crystal structure, physical properties and Pt-195 NMR characterization of Pt(bipy)Br₂

David A. Sartori, Stephanie K. Hurst, Nathan Wood, Raymond D. Larsen, Edwin H. Abbott

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The complex dibromobipyridylplatinum(II), Pt(bipy)Br₂, crystallizes in the monoclinic space group C2/c with a = 17.262(5) Å, b = 9.388(2) Å, c = 7.557(2) Å, β = 113.47(2)°, and Z = 4. The complex is isomorphous to the monomeric copper derivative, Cu(bipy)Br ₂. The ¹⁹⁵Pt NMR spectrum shows the typical line broadening effect caused by coordinated nitrogen-14. The complex resonates at -1897 ppm with a half-height peak width of 1300 Hz. The structure is compared with the analogous structures Pt(bipy)(X)₂ (X = Cl and I) and Pd(bipy)Br₂.

Original language	English (US)
Pages (from-to)	995-998
Number of pages	4
Journal	Journal of Chemical Crystallography
Volume	35
Issue number	12
DOIs	https://doi.org/10.1007/s10870-005-5837-x
State	Published - Dec 2005

Keywords

Bipy
Bipyridyl
Platinum(II) complex
Pt-195 NMR

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics

Access to Document

10.1007/s10870-005-5837-x

Cite this

@article{ad3fb8905e7149228da1d38916d1e801,

title = "Crystal structure, physical properties and Pt-195 NMR characterization of Pt(bipy)Br2",

abstract = "The complex dibromobipyridylplatinum(II), Pt(bipy)Br2, crystallizes in the monoclinic space group C2/c with a = 17.262(5) {\AA}, b = 9.388(2) {\AA}, c = 7.557(2) {\AA}, β = 113.47(2)°, and Z = 4. The complex is isomorphous to the monomeric copper derivative, Cu(bipy)Br 2. The 195Pt NMR spectrum shows the typical line broadening effect caused by coordinated nitrogen-14. The complex resonates at -1897 ppm with a half-height peak width of 1300 Hz. The structure is compared with the analogous structures Pt(bipy)(X)2 (X = Cl and I) and Pd(bipy)Br2.",

keywords = "Bipy, Bipyridyl, Platinum(II) complex, Pt-195 NMR",

author = "Sartori, {David A.} and Hurst, {Stephanie K.} and Nathan Wood and Larsen, {Raymond D.} and Abbott, {Edwin H.}",

note = "Funding Information: The work described in this paper was supported by The Associated Western Universities, the Inland Northwest Research Alliance, and the United States Department of Energy through contract no. DE-AC07-99ID13727.",

year = "2005",

month = dec,

doi = "10.1007/s10870-005-5837-x",

language = "English (US)",

volume = "35",

pages = "995--998",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer New York",

number = "12",

}

TY - JOUR

T1 - Crystal structure, physical properties and Pt-195 NMR characterization of Pt(bipy)Br2

AU - Sartori, David A.

AU - Hurst, Stephanie K.

AU - Wood, Nathan

AU - Larsen, Raymond D.

AU - Abbott, Edwin H.

N1 - Funding Information: The work described in this paper was supported by The Associated Western Universities, the Inland Northwest Research Alliance, and the United States Department of Energy through contract no. DE-AC07-99ID13727.

PY - 2005/12

Y1 - 2005/12

N2 - The complex dibromobipyridylplatinum(II), Pt(bipy)Br2, crystallizes in the monoclinic space group C2/c with a = 17.262(5) Å, b = 9.388(2) Å, c = 7.557(2) Å, β = 113.47(2)°, and Z = 4. The complex is isomorphous to the monomeric copper derivative, Cu(bipy)Br 2. The 195Pt NMR spectrum shows the typical line broadening effect caused by coordinated nitrogen-14. The complex resonates at -1897 ppm with a half-height peak width of 1300 Hz. The structure is compared with the analogous structures Pt(bipy)(X)2 (X = Cl and I) and Pd(bipy)Br2.

AB - The complex dibromobipyridylplatinum(II), Pt(bipy)Br2, crystallizes in the monoclinic space group C2/c with a = 17.262(5) Å, b = 9.388(2) Å, c = 7.557(2) Å, β = 113.47(2)°, and Z = 4. The complex is isomorphous to the monomeric copper derivative, Cu(bipy)Br 2. The 195Pt NMR spectrum shows the typical line broadening effect caused by coordinated nitrogen-14. The complex resonates at -1897 ppm with a half-height peak width of 1300 Hz. The structure is compared with the analogous structures Pt(bipy)(X)2 (X = Cl and I) and Pd(bipy)Br2.

KW - Bipy

KW - Bipyridyl

KW - Platinum(II) complex

KW - Pt-195 NMR

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U2 - 10.1007/s10870-005-5837-x

DO - 10.1007/s10870-005-5837-x

M3 - Article

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EP - 998

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

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