Bis(tetraphenylphosphonium) di-μ-iodido-bis[diiodidopalladate(II)]

Frank Mulligan; Gary S. Nichol; Stephanie K. Hurst

doi:10.1107/S160053680704528X

Bis(tetraphenylphosphonium) di-μ-iodido-bis[diiodidopalladate(II)]

Frank Mulligan, Gary S. Nichol, Stephanie K. Hurst

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The title compound, (PPh4)2[Pd2I6], was obtained unintentionally as the product of an attempted synthesis of a tripalladium sandwich complex. The mol-ecular dimensions are unexceptional and the Pd⋯Pd distance, at 3.8183 (12) Å, is much too long for any Pd - Pd inter-action. Pd has a typical square-planar coordination geometry and the centrosymmetric anion is essentially planar.

Original language	English (US)
Pages (from-to)	m2558
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	10
DOIs	https://doi.org/10.1107/S160053680704528X
State	Published - Oct 15 2007

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S160053680704528X

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abstract = "The title compound, (PPh4)2[Pd2I6], was obtained unintentionally as the product of an attempted synthesis of a tripalladium sandwich complex. The mol-ecular dimensions are unexceptional and the Pd⋯Pd distance, at 3.8183 (12) {\AA}, is much too long for any Pd - Pd inter-action. Pd has a typical square-planar coordination geometry and the centrosymmetric anion is essentially planar.",

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AU - Nichol, Gary S.

AU - Hurst, Stephanie K.

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N2 - The title compound, (PPh4)2[Pd2I6], was obtained unintentionally as the product of an attempted synthesis of a tripalladium sandwich complex. The mol-ecular dimensions are unexceptional and the Pd⋯Pd distance, at 3.8183 (12) Å, is much too long for any Pd - Pd inter-action. Pd has a typical square-planar coordination geometry and the centrosymmetric anion is essentially planar.

AB - The title compound, (PPh4)2[Pd2I6], was obtained unintentionally as the product of an attempted synthesis of a tripalladium sandwich complex. The mol-ecular dimensions are unexceptional and the Pd⋯Pd distance, at 3.8183 (12) Å, is much too long for any Pd - Pd inter-action. Pd has a typical square-planar coordination geometry and the centrosymmetric anion is essentially planar.

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ER -

Bis(tetraphenylphosphonium) di-μ-iodido-bis[diiodidopalladate(II)]

Abstract

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