A 58-electron superatom-complex model for the magic phosphine-protected gold clusters (Schmid-gold, Nanogold®) of 1.4-nm dimension

Keyphrases

• Phosphine 100%
• Model Complexity 100%
• Gold Clusters 100%
• Superatoms 100%
• Nanogold 100%
• Electron Shell 66%
• Strong Correlation 33%
• Mass Spectrometry 33%
• Anions 33%
• Halides 33%
• Density Functional Theory 33%
• Gold Core 33%
• Core Size 33%
• Cluster Size 33%
• Atomic Clusters 33%
• Gold Atoms 33%
• Ligand-protected Clusters 33%
• Atomic Size 33%
• Structural Identity 33%
• Formation Energy 33%
• Adatoms 33%
• Delocalized Electrons 33%
• Optimal Energy 33%
• NMR Spectrometry 33%

Chemistry

• Phase Composition 100%
• Density Functional Theory 50%
• Structure 50%
• Halide 50%
• NMR Spectroscopy 50%
• Energetics 50%
• Mass Spectrometry 50%
• Standard Model 50%
• Adatoms 50%
• Gold Atom 50%
• Molecular Cluster 50%